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Filtering by: Creator Neng Guo Resource type Dissertation

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Bimetallic Effects in the Homopolymerization of Styrene and Copolymerization of Ethylene and Styrenic Comonomers. Scope, Kinetics, and Mechanism/Catalytic In Situ Synthesis of High Energy Storage Density Metal Oxide-Polyolefin Nanocomposites Using Supported Metallocenes. Systematics of Nanoparticle, Shape, and Interfacial Characteristics on Leakage Current Density, Permittivity, and Breakdown Strength

Description:

Chapter 1 describes the homopolymerization of styrene and the copolymerization of ethylene and styrenic comonomers mediated by the single-site bimetallic "constrained geometry catalysts" (CGCs), (µ-CH2CH2-3,3'){(η5-indenyl)[1-Me2Si(tBuN)](TiMe2)}2 [EBICGC(TiMe2)2; Ti2], (µ-CH2CH2-3,3'){(η5-indenyl)[1-Me2Si(tBuN)](ZrMe2)}2 [EBICGC(ZrMe2)2; Zr2], (µ-CH2-3,3'){(η5-indenyl)[1-Me2Si(tBuN)](TiMe2)}2 [MBICGC(TiMe2)2; C1-Ti2], and (µ-CH2-3,3'){(η5-indenyl)[1-Me2Si(tBuN)](ZrMe2)}2 [MBICGC(ZrMe2)2; C1-Zr2], in combination with the borate activator/cocatalyst Ph3C+B(C6F5)4- (B1). Under identical styrene homopolymerization conditions,...

Keyword:

Inorganic Chemistry

Subject:

Chemistry

Creator:

Neng Guo

Owner:

Scholarly Digital Publishing

Date Uploaded:

08/30/2018

Date Modified:

08/30/2018

Date Created:

2007-10-01

Resource Type:

Dissertation