This dissertation presents a comprehensive study of thin-film LiMn2O4 (LMO) cathodes applied in lithium ion batteries (LIBs). The primary aim was to establish fundamental understanding of the relationship between interfacial LMO chemistry/electrochemistry and its detrimental drawback, i.e. fast capacity fade over long term cycling, and then develop effective mitigation methods....
The anode and cathode are main components in a battery system. In this dissertation, Group IV inter-metallics and LiMn2O4 are studied as anode and cathode materials for Li-ion batteries respectively. Preliminary investigation of a multi-valent cathode material for next generation batteries is also introduced.
Group IV inter-metallics electrochemically alloy with...